Stabilization of pi-conjugated organoboron scaffolds by structural constraint
نویسندگان
چکیده
منابع مشابه
Chiral -conjugated organoboron polymers*
A novel π-conjugated organoboron polymer with a chiral side chain was prepared by way of hydroboration polymerization between an optically active diyne monomer and triisopropylphenylborane. The achiral analog of this organoboron polymer was also prepared as reference material. Optical properties and optical activity were investigated by UV–vis absorption, fluorescence emission, and circular dic...
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The line-dipole approximation is used to investigate the scaling of the groundstate dispersion interaction, EW, between parallel conjugated polymers of length L and transverse separation D. Both a second-order perturbation theory calculation using the Mott-Wannier exciton model of excited states and a semiclassical analysis of distributed dipoles indicate that at L approximately D there is a cr...
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2013
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0014.106